![]() ![]() ![]() Some materials like Silicon, germanium, bismuth, and water are less dense in solid form than in liquid form. Therefore, the ρ solid > ρ liquid > ρ gas Solid atoms or molecules are more closely packed together than liquid atoms or molecules. In general, a solid mass of a substance sinks when immersed in a liquid of the same substance. The less-dense stuff floats on top of the dense liquid.īecause the ρwater of ice is smaller than the ρwater of water, ice floats on water. The density of water (g/ml) = 8kg/(8 x10-3 m3 ) The mass (m) of 8 liters of water is 8 kg. Specific weight (γ) = (ρ x volume x g)/volume It is represented by the symbol γ.Īt 4☌, the specific weight of water on earth is 9.807 kN/m 3 = 62.43 lbs/ft 3.Ĭheck the full article “Specific gravity of water”. The specific weight of water is the weight of water per unit volume. ![]() There are three different Units of Gallon: Weight of a Gallon of Water Weight of 1 liter (l) of pure water (at 4 ☌) = 1 kilogram (kg). The weight of a gallon of water depends upon storing the temperature of the water, For the sake of the question, ‘How much does a gallon of water weigh?’, we are going to focus on the weight of water at 62 ☏ (17 ☌).ġ US gal of water = 8.345 pounds = 3.785 kg (at 17 ☌).ġ Imperial gal of water = 10.02 pounds = 4.545 kg (at 17 ☌). At 4☌, the density of fresh water on Earth is generally understood to be 1000 kg/m 3. However, this value varies depending on the temperature and impurities in the water.Ĭommon units of ρ water are grams per milliliter (1 g/ml), grams per cubic centimeter ( g/cm 3), and pounds per cubic foot (lb/ft 3). The density of water (ρ water) is around 8.345 lbs/U.S. This is since iron has a greater amount of substance than wood.ĭensity (ρ) formula = mass (m) of substance ÷ volume (v) of substance The density of water in lbs/U.S. We’ll find that iron is heavier than wood. It is the mass-to-volume ratio of the material. How much does a gallon of water weigh at its highest density?ĭensity refers to the amount of substance per unit volume.The density of Water in g/ml (Effect of Temperature).Calculating the specific weight of water.Read more about how to correctly acknowledge RSC content. Please go to the Copyright Clearance Center request page. In a third-party publication (excluding your thesis/dissertation for which permission is not required) If you want to reproduce the whole article If you are the author of this article, you do not need to request permission to reproduce figuresĪnd diagrams provided correct acknowledgement is given. Provided correct acknowledgement is given. If you are an author contributing to an RSC publication, you do not need to request permission To request permission to reproduce material from this article, please go to the ![]() Indanone-based conjugated polymers enabling ultrafast electron transfer for visible light-driven hydrogen evolution from water This study provides valuable insights into the potential of IC-based conjugated polymers for photocatalytic hydrogen evolution. As a result, ICTDB, photocatalysts with IC-containing structures achieved a hydrogen evolution rate of 30.0 mmol g −1 h −1, which was 11.5 times higher than that of ICFTDB, the polymer with no malononitrile substitution. Through transient absorption spectroscopy, we demonstrated that ICTDB exhibited enhanced capabilities for ultrafast electron transfer and reduced recombination effects. We investigated the correlation between the optical, electrochemical, and hydrogen evolution performances of these polymers. These monomers were used to synthesize polymers with varying degrees of malononitrile substitution, referred to as ICFTDB, ICTDB, and IDMTDB. In this study, we designed a series of novel IC-based monomers incorporating a dibenzothiophene- S, S-dioxide unit through Suzuki coupling. However, research on the application of IC structures in PHP is limited due to synthesis challenges. 1,1-dicyanomethylene-3-indanone (IC) has been widely used as an end group in organic photovoltaics owing to its strong electron-withdrawing ability and planarity. Photocatalytic hydrogen production (PHP) from water is a promising solution for environmental pollution due to its high energy density and the abundant availability of water and solar energy on Earth. ![]()
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![]() ![]() A message can flow in any direction from left to right, right to left, or back to the Message Caller itself. The use of the activation bar on the lifelines of the Message Caller (the object that sends the message) and the Message Receiver (the object that receives the message) indicates that both are active/ are instantiated during the exchange of the message.Īn arrow from the Message Caller to the Message Receiver specifies a message in a sequence diagram. In a sequence diagram, an interaction between two objects occurs when one object sends a message to another. The length of the rectangle indicates the duration of the objects staying active. It is used to indicate that an object is active (or instantiated) during an interaction between two objects. The activation bar is the box placed on the lifeline. It organizes and schedules the interactions between the boundaries and entities and serves as the mediator between them. For example, in a customer service application, the Customer entity would manage all data related to a customer.Ī lifeline with a boundary element indicates a system boundary/ software element in a system for example, user interface screens, database gateways or menus that users interact with, are boundaries.Īnd a lifeline with a control element indicates a controlling entity or manager. They represent the different objects or parts that interact with each other in the system during the sequence.Ī lifeline notation with an actor element symbol is used when the particular sequence diagram is owned by a use case.Ī lifeline with an entity element represents system data. No two lifeline notations should overlap each other. A Quick Overview of the Various Parts of a Sequence Diagram Lifeline NotationĪ sequence diagram is made up of several of these lifeline notations that should be arranged horizontally across the top of the diagram. Each object has a column and the messages exchanged between them are represented by arrows. Sequence Diagram NotationsĪ sequence diagram is structured in such a way that it represents a timeline that begins at the top and descends gradually to mark the sequence of interactions. They can be used to model both simple and complex interactions between objects, making them a useful tool for software architects, designers, and developers. Sequence diagrams are commonly used in software development to illustrate the behavior of a system or to help developers design and understand complex systems. In simpler words, a sequence diagram shows how different parts of a system work in a ‘sequence’ to get something done. They illustrate how the different parts of a system interact with each other to carry out a function, and the order in which the interactions occur when a particular use case is executed. Sequence diagrams, commonly used by developers, model the interactions between objects in a single use case.
![]() ![]() He's a very clear writer, with a remarkable ability to explain things in words like very few others can. He's highly regarded in the world of magic not just for the tremendous entertainment he has provided to thousands of audiences across the world, but especially for his contributions in teaching magic. Some of the tricks featured in that lecture were from his 2015 book, called Jaw Droppers!īut Mr Lorayne wasn't done writing yet. You can purchase access to this great 3 hour lecture and interview for just $5 (see details in my review here), which includes performances and teaching of some of his all time favourites, as well as some of his new material. In 2016, in connection with his 90th birthday, he delivered a lecture entitled The Jaw Droppers Lecture, which displayed that he still has remarkable skills in card manipulation, and more importantly in showmanship and entertainment. Here's a picture of Harry in his hey-day:īut even at 92, Harry Lorayne is still active. He's also made significant contributions to the art of memory training, a field in which he is typically regarded as the world's foremost expert. A top showman of his time, he is an incredible magician who has made a prolific and lasting contribution to the art of card magic. His excellent book on magic for beginners, The Magic Book (1977) and his first work on card magic, Close-Up Card Magic (1962), both continue to be included by many magicians in their lists of all-time favourite books on magic. ![]() In the course of his life, he has sold more than 17 million copies of over 40 books, including many classic works of magic. But if his latest book, Jaw Droppers! Two is any indication, I'm hoping he won't go away any time soon! We can only be grateful that he is still contributing new material to the world of magic.īorn in 1926, the celebration of Harry Lorayne's 92nd birthday means that this living legend of magic has outlived nearly all his contemporaries. He's 92 years old as of today,, and he's still making a lot of noise. Mr Harry Lorayne doesn't go away quietly. Over seventy great tricks in the newest book from living legend Harry Lorayne! ![]() ![]() ![]() The gameplay in gta5 getintopc is incredibly diverse, offering a wide range of activities to engage in. Players can switch between these characters at any time, allowing them to experience the game from different perspectives. Each character has their own unique personality, storylines, and abilities, creating a dynamic and engaging narrative. In gta5 getintopc, players can take on the roles of three distinct protagonists: Michael, Franklin, and Trevor. ![]() The game provides a vast open-world environment set in the fictional city of Los Santos and its surrounding areas, offering players a rich and detailed world to explore. G ta5 getintopc offers an immersive and thrilling gameplay experience that has captivated players worldwide. These platforms provide legitimate copies of the game, ensuring that you have access to the latest updates and support. To play GTA 5 on your PC, you can purchase the game through official platforms such as the Rockstar Games website, authorized online retailers, or digital distribution platforms like Steam or Epic Games Store. It is available for PC users running Windows operating systems, including Windows 11, Windows 10, Windows 8, and Windows 7. Grand Theft Auto V, commonly known as gta5 getintopc, is a highly acclaimed action-adventure video game developed by Rockstar North. Each character has their own unique personality and storyline, adding depth and diversity to the overall gaming experience. One of the most remarkable features of gta5 getintopc is its highly immersive gameplay, which allows players to take on the roles of three distinct protagonists: Michael, a retired bank robber dealing with family issues Franklin, a street-smart hustler looking for opportunities and Trevor, a volatile and unpredictable character with a penchant for chaos. Set in the sprawling fictional city of Los Santos, GTA 5 offers players a vast open-world environment where they can engage in thrilling missions, explore the city, and partake in various criminal activities. Grand Theft Auto V, commonly known as gta5 getintopc, is an immensely popular action-adventure video game developed by Rockstar North. ![]() ![]() ![]() ![]() If you don't have children to take to go see this film then take friends who saw the first two films. The ending was so tough to watch without sniffling because if you watched Toy Story at around Andy's age during the time and you watch Toy Story 3 around Andy's age now (he was 17 and I am 22 and went through roughly the same hassle as he did when he was moving out for college), you would feel a wallop of emotion. ![]() This was the second instance where Disney did not release the award-winning soundtrack of a Pixar film on CD, with the first being Up. Initially, Disney released the soundtrack only as digital download. I related to Andy in this film just as I did in Toy Story 3. The Toy Story 3 soundtrack was composed by Randy Newman.It was released on June 15, 2010, three days before the movie. I have no idea how Disney and Pixar knock out great movies like this (they make it look easy). The visuals were stunning! The script was enjoyable! This movie reached all corners of film greatness (and its a kid's movie). But Toy Story 3 set the bar "to infinity and beyond!" The VA cast was pheNOMenal. Toy Story 2, in my opinion, was not as good as its first installment but it was a film that almost never hit theaters so I'll give them the benefit of doubt. It is in this film that the Myth Arc of the series - which. Andynow almost 18is getting ready for college, and the plot follows the adventures of Andy's childhood toys as they're accidentally donated to a preschool/daycare center for a new generation of kids to enjoy, much to the toys' dismay. Toy Story was a smash hit when it first hit the screens. Toy Story 3 is the 2010 sequel to Toy Story 2. Lots of drama, lots suspense, and lots of toys! Disney and Pixar outdid themselves with this one. He was once one of Daisys toys before he, Lotso, and Chuckles were lost, and came to Sunnyside Daycare. Hence his name, he is a very big baby doll, about the size of an actual baby. This film was a carelessly thoughtful stoke of genius! It keeps both children and adults entertained. Mama.Big Baby Big Baby is one of the secondary antagonists of Disney/Pixars 2010 animated film Toy Story 3. I asked myself why did my mother give away my toys without my permission? At THAT moment is when I thought about the last 30 minutes of Toy Story 3 I started to cry. My conner only housed my stack of video games. It was more than just a 'toy story', it was a trilogy about the love of a family made of imperfect 'people' working together through love. I went home walked into my room a realized that my Optimus Prime is not at the foot of my door, my Sylvester the Cat stuffed toy was not on my bed, and my McDonald's Sonic the Hedgehog toy was not on my shelf. In essence, these sort of friends who love of this deeply are more than friends, they are our family through love, as the toys recognized themselves as a family. Listen to all 42 songs from the Toy Story 3 soundtrack, playlist, ost and score. The other Disney film that came close was Pixar's WALL E. The only Disney movie I cried in was Lion King. ![]() ![]() ![]() Let's take a look at some of the Field Pass Players you can begin earning and upgrading! In case you missed our GMM Broadcast last night, Season 4 goes live today. Over 600 player and generic portrait updates.Improved performance of many UI transitions.Corrected various visual bugs and text overlaps.Fixed an issue where the wrong playbooks were being used in MUT Practice Mode.Fixed an issue with leaderboards that were not updating data when switching between this week and previous week.Fixed an issue that would cause some users to become stuck on the archive tab in field pass.Fixed a crash that would happen if the user clicked the “Show Quicksell” button on a locked pack in the New Item Flow.However, please note we strongly recommend that you start a new Franchise file for Crossplay in the event our team would need to temporarily disable the feature during the live beta. DEV NOTE: Please note that this feature is in live beta and can be implemented in any league. ![]() Check the League Settings to enable Crossplay* today! Crossplay is available on Xbox Series X|S, PlayStation®5, and PC platforms.* Internet connection, all game updates & EA account required. With our Franchise Cross Play Live Beta, Cloud Franchise leagues can now include users of all supported Crossplay platforms.Now if a defender who is not a dedicated pass rusher having a Power Move and Finesse Move rating below 70 engages in a blocking mismatch where they are outweighed by 90 lbs or more, they will suffer a significant fatigue hit. DEV NOTE: With the prevalence of Defensive Back blitzes being used as staple defenses, we noticed that there were many cases where the DB would get picked up by a Tight End or an Offensive Lineman that was significantly bigger and stronger than the defensive back but the blitzing DB would be able to engage in this mismatch over and over again without fatiguing.Tuning to fatigue logic so defenders who are not dedicated pass rushers will suffer a more severe fatigue penalty when engaging with a pass blocker that is significantly bigger than them.Fixed an issue where the Conductor Ability was not granting the user 2 adjustments as the QB was walking to the line.This fix will allow pass rushers to use pass-rush moves that trigger before they get engaged by a blocker. ![]()
![]() It features an urban setting where players must fight each other with a range of weapons like. You can build everything in Blockstorm, and you can destroy it. Krunker is a free first-person shooter game for Windows. Top free games - Shop these 90 items and explore Microsoft Store for great apps, games, laptops, PCs, and other devices. "All maps and characters included in the game are made with the same tools that are available to the public. Gunship Force: Battle of Helicopters Online. Paint Warfare latest version: A simple first-person shooter to play with friends. " Blockstorm is a FPS game set in a world made of destructible blocks," reads an official blurb about the game for those unfamiliar with it. We hope that going free-to-play, our gift to all of our loyal fans and involved community, will encourage even more players to join the Blockstorm community and enjoy the game." This World War II shooter game has been popular among gamers. We want to thank our dedicated community of players for their support and feedback over the years. Call of Duty Mobile for PC is the Windows version of the popular battle royale game series. This means that everyone can now experience the adrenaline rush of shooting and building their way through the game's dynamic levels without having to pay a penny. ![]() Resident Evil 4 paved the way for third-person shooters by marrying responsive. "From today onwards, players can download and play Blockstorm for free on Steam. One of the most influential action-shooters received the Capcom remake glow-up. "We are excited to announce that Blockstorm, the voxel first-person shooter game, our first passion project (but not our last), is now free to play on Steam, forever and for everyone," reads the announcement from GhostShark. Want to play Shooting Games Play Bullet Force Multiplayer, Combat Online, Mad GunZ and many more for free on Poki. ![]() ![]() ![]() Partners often develop unique systems for signaling via bidding, but a commonly used pattern works as follows: In Pinochle, it is a valid strategy to use your bid to signal something about your hand to your partner. If you want to improve your skills even more, read through our Double Deck Pinocle strategy guide for in-depth tips and tricks to the game. ![]() We've summed up the most important strategic points below. Furthermore, you want to get good at managing trump suits and meld points to maximize your trick-taking and scoring opportunities. Much of the strategy revolves around signaling your partner through the bidding process to develop unique systems to communicate hand strength. Strategyĭouble Deck Pinochle is a game of communication. Tricks are played in clockwise order, with players needing to play higher-ranking cards if possible. ![]() The highest bidder chooses the trump suit and must have a marriage (King and Queen) in that particular suit. Each team must score no less than 20 points in both melds and tricks to avoid penalties.Īt the start of the game, each player is dealt 20 cards, and the trump suit is determined by having each player bid. Kings, Aces and 10s are each worth 1 point in a trick, and the last trick has a bonus of 2 points. Points are earned through melding and trick-taking. The goal of the game is to reach 500 points first. On that page, you'll also find an interactive tutorial that'll teach you the rules by having you play a game while explaining the rules.ĭouble Deck Pinochle is a 4-player game where the players are split into 2 teams of 2 players. For people new to the game, we suggest going through our in-depth guide on how to play Double Deck Pinochle. If you're in need of brushing up on the rules of Double Deck Pinochle, we've summed them up below. ![]() ![]() ![]() He ignored the reports until they started to affect his family’s health. The rumors emerged after Charles moved to the Phoenix Suns, leaving Maureen and Christiana in Philadelphia.Ĭharles was linked with Madonna after the pair met once in Phoenix. In the early 90s, Charles Barkley was linked with singer Madonna. Barkley said that his reports linking him to Madonna contributed to Maureen’s mom’s heart attack Blumhardt currently focuses on philanthropy and women empowerment – she is an honorary member of a non-profit organization in Phoenix named ‘Fresh Start Women’s Foundation.’Ĭhristiana is also a member of the Fresh Start Women’s Foundation. “Fresh Start Women’s Foundation provides education, resources and support for women to positively transform their lives and strengthen our community,” the organization’s website reads. Maureen studied journalism but became a model and, later, a legal aid. She didn’t even want to come to the game because she didn’t want to jinx the game.” She’s been going to a Villanova bar in New York City every game. “My daughter was living and dying with every game for the last three weeks, so I was really more excited for her, to be honest with you. ![]() However, Barkley told USA Today that he was happy for his daughter’s team: Initially, people thought his celebrations stemmed from his strained relationship with Michael Jordan, a North Carolina alum. In April 2016, Barkley was seen cheering fervently for Villanova following the team’s victory over North Carolina. Charles supports Villanova’s basketball team as his wife and daughter graduated from the school. The pair attended Villanova University and, later, Columbia Journalism School to study journalism. I just liked the mall.” Christiana was born during Barkley’s time with the Philadelphia 76ers.Ĭhristiana and her mother followed a similar higher education path. “There’s a Christiana Mall in Delaware that I always used to go by,” Barkley said. “That’s how she got her name, Christiana. Charles said on The Steam Room podcast that the couple got their daughter’s name from a mall in Delaware. My husband started a swear jar a year and a half ago so…” The couple welcomed their daughter in 1989 and named her after a mallīarkley and Maureen welcomed their daughter, Christiana Barkley, in 1989. She recently made fun of Charles’s affinity for swearing via the following tweet: “I finally figured out the reason behind the coin shortage. I told him that would be a grave mistake.” “This quarantine!” Maureen tweeted in May 2020. “C told me that if I try to take control of the TV remote again…that he’ll bury me alive. She is quite the comedian on Twitter, with some of her posts offering a glimpse into her life with Barkley. Maureen’s secret to a happy marriage is seemingly humor. She doesn’t judge, accepts me how I am, she’s a great mother.” I think the main reason is she accepts my flaws and all. Charles told former WWE presenter Renne Paquette that his marriage has lasted for more than three decades, largely thanks to Maureen. Interracial marriages are now more common, but the racial climate in the United States is still hostile. If you are Hispanic, you are going to be some type of gangbanger. If you are some type of Muslim, you are going to be blowing stuff up. ![]() “If you are black on television, you are probably going to be some kind of thug, gangster or portrayed in a negative light. Despite the controversy, Maureen and Charles married in 1989.īarkley told Sports Illustrated that he hated the stereotypes attached to non-White people. Philly had allegedly not accepted interracial relationships, let alone interracial marriages. The couple reportedly faced backlash for pursuing an interracial relationship. | Vinnie Zuffante/Michael Ochs Archives/Getty Images Charles Barkley and Maureen Blumhardt in a branch of Planet Hollywood, location unspecified, 1994. Barkley was playing for the 76ers, and Maureen was a legal aid. Maureen and Barkley met in the 1980s and married in 1989Ĭharles Barkley and Maureen Blumhardt met in the 1980s at a restaurant named City Avenue in Pennsylvania. This piece looks at Charles Barkley’s wife, Maureen Blumhardt. Barkley’s overt celebrations and taunts must have stung Smith, who couldn’t bear to look at the dancing Chuckster.īarkley’s career exploits are well-documented, but he rarely discusses his personal life. Smith, a North Carolina alum, was disappointed by the result, and Barkley was on hand to rub his face in it. Barkley foretold a Kansas Jayhawks win against the North Carolina Tar Heels.įollowing a stirring comeback, the Jayhawks won, validating Charles’ prediction. Barkley’s colleague Kenny Smith recently found himself on the wrong side of a correct prediction by Charles. Charles Barkley is an NBA legend known by current NBA fans for his antics and predictions as an NBA analyst. ![]() ![]() ![]() \root\Licenses16\proplusvl_kms*.xrm-ms') do cscript ospp.vbs /inslic:".\root\Licenses16\%%x" >nul)&(for /f %%x in ('dir /b. Title Activate Microsoft Office 2016 ALL versions for FREE!&cls&echo =&echo #Project: Activating Microsoft software products for FREE without software&echo =&echo.&echo #Supported products:&echo - Microsoft Office Standard 2016&echo - Microsoft Office Professional Plus 2016&echo.&echo.&(if exist "%ProgramFiles%\Microsoft Office\Office16\ospp.vbs" cd /d "%ProgramFiles%\Microsoft Office\Office16")&(if exist "%ProgramFiles(x86)%\Microsoft Office\Office16\ospp.vbs" cd /d "%ProgramFiles(x86)%\Microsoft Office\Office16")&(for /f %%x in ('dir /b. Step 2: Click on "Install Now" and by default, Windows will install MS Office Suite in the default C:\Prorgam off Accept terms and conditions and then click "Continue". ![]() Step 1: To install MS Office 2016, run the setup.exe file. Follow these simple steps to install the suite. Once you have extracted the ISO file, you should get a list of files, one of them is a setup.exe file. Keep in mind that the ISO file is used to burn CD or DVD, but you can also install Office 2016 without having to burn it using 7-Zip or another archive program. "SW_DVD5_Office_Professional_Plus_2016_W64_English…" for the 64-bit ![]() "SW_DVD5_Office_Professional_Plus_2016_W32_English…" for the 32-bit Once the download is complete, you need to extract the ISO image from the zip files named: You can get the latest version of Microsoft Office from the official Microsoft website here. The following are some Microsoft Office 2016 Product keys that will work for programs downloaded or purchased in 2019. Either way, you will need the product key before you can activate the program. The suite can be preinstalled on your computer or you can download it from an online store or even purchase it from a physical store. How you acquired your Microsoft Office 2016 suite will determine how you get the product key. This code is what is known as the Microsoft Office Product Key and it's usually in the following format: When you purchase your Microsoft Office 2016 suite and install it on your computer for the first time, you will be required to enter a 25-character code. The different retail suites of Microsoft Office 2016 include: You will be able to access online and offline versions of MS Office.Ī retina display makes the use of these programs much more pleasant. The following are just some of the features you can expect to enjoy when you activate the new Microsoft office 2016 product key:ĭocument creation, editing and opening will be much easier. The programs are also running much more smoothly. Most users are praising the much improved interface that has made it easier to create documents. Microsoft has also gone a step further and given the individual programs in the suite a face lift. Updates of the Microsoft Office 2016 suite will also be available to users for free every month. Along with the new features, Microsoft has also included a much more improved version of the Data loss Protection (DPL) in the software. The latest version of Microsoft Office 2016 was released in January 2018, including the latest version of all the programs under that suite. Tip: Forgot Official File Password? How to Recover the Password 1. Activate MS Office 2016 without a Product Keyħ. Activating Microsoft Office 2016 Using a Product KeyĦ. How to Download Original MS Office 2016 ISOĥ. What is Microsoft office 2016 Product KeyĤ. ![]() |
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